Morpholinium 2,4,6-trinitrophenolate

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In the title salt, C(4)H(10)NO(+)·ClO(4) (-), which has three independent formula units, the cations are linked into chains along [100] by N-H⋯O hydrogen bonds. Each cation acts both as a donor and as an acceptor, and every cation makes one N-H⋯O hydrogen bond with a ClO(4) (-) anion. The crystal studied was an inversion twin.

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In the title mol-ecular salt (systematic name: morpholinium 3-hy-droxy-2,4,6-trinitro-phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (-), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra-molecular O-H⋯O hydrogen bond occurs in the anion. ...

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Morpholinium 2,4,6-trinitro­phenolate

There are two independent formula units in the asymmetric unit of the title compound, C(4)H(10)NO(+)·C(6)H(2)N(3)O(7) (-). The morpholinium cations in both mol-ecules are puckered and adopt a chair conformation. Intermolecular N-H⋯O and C-H⋯O inter-actions generate rings of motifs R(2) (1)(5) and R(1) (2)(6). The supra-molecular aggregation is completed by the presence of two co-operative hydro...

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In the crystal structure of the title compound, C(4)H(10)NO(+)·C(6)HCl(2)O(4) (-)·CH(4)O, the components are held together by bifurcated O-H⋯(O,O), O-H⋯(O,Cl) and N-H⋯(O,O) hydrogen bonds into a centrosymmetric 2+2+2 aggregate. The aggregates are further connected by another bifurcated N-H⋯(O, O) hydrogen bond, forming a double-tape structure along the b axis. A weak C-H⋯O inter-action is obser...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808042657